Diana Rigg – On Her Majesty’s Secret Service (1969)
Rigg was already well known for playing agent Mrs. Emma Peel in The Avengers TV series before becoming Bond girl Tracy Di Vicenzo in On Her Majesty’s Secret Service. Rigg has since had an extensive career in acting and has recently appeared in Game of Thrones. In 1994 she won a Tony Award for Best Actress In A Play for her title role in Medea. Given her successes, Rigg was made a Commander of the Order Of The British Empire (CBE) in 1988 and a Dame Commander of the Order Of The British Empire (DBE) in 1994.